JEE Advanced 2022 Paper 2 · Q11 · Surface Tension
A bubble has surface tension $S$. The ideal gas inside the bubble has ratio of specific heats $\gamma = 5/3$. The bubble is exposed to the atmosphere and it always retains its spherical shape. When the atmospheric pressure is $P_{a1}$, the radius of the bubble is found to be $r_1$ and the temperature of the enclosed gas is $T_1$. When the atmospheric pressure is $P_{a2}$, the radius of the bubble and the temperature of the enclosed gas are $r_2$ and $T_2$, respectively. Which of the following statement(s) is(are) correct?
Reveal answer + step-by-step solution
Correct answer:C, D
Solution
A soap bubble has two surfaces, so the pressure inside exceeds outside by $4S/r$ (single-film bubble would give $2S/r$). Let $P_{\text{in},i} = P_{ai} + 4S/r_i$. (C) Heat conductor (isothermal): $P_{\text{in},1} V_1 = P_{\text{in},2} V_2 \Rightarrow (P_{a1}+4S/r_1) r_1^3 = (P_{a2}+4S/r_2) r_2^3$, giving $r_1/r_2 = ((P_{a2}+4S/r_2)/(P_{a1}+4S/r_1))^{1/3}$ — correct. (D) Heat insulator (adiabatic, $\gamma = 5/3$): $P_{\text{in}}V^\gamma = $ const and $T V^{\gamma-1} = $ const, so $T \propto P^{(\gamma-1)/\gamma} = P^{2/5}$. Hence $T_2/T_1 = ((P_{a2}+4S/r_2)/(P_{a1}+4S/r_1))^{2/5}$ — correct. (A) Statement uses $2S/r$ (wrong factor for bubble) and exponent $5/2$ instead of the correct adiabatic exponent $3/5$ (since $r^3 \propto V \propto P^{-1/\gamma}$ gives $r_1/r_2 = (P_{\text{in},2}/P_{\text{in},1})^{1/(3\gamma)} = (\cdot)^{1/5}$) — incorrect. (B) For an adiabatic transformation, the gas does work against the atmosphere and against surface tension; the internal energy + surface energy does change — incorrect. Official key: (C), (D).
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